scroll to top
Your source for trusted research content

EBSCO Auth Banner

Let's find your institution. Click here.

Coordination polymer chains built from Cu(II) and adipate ions linked by hydrogen bonds to form a three-dimensional framework structure.

  • Academic Journal
  • Setifi Z; Département de Technologie, Faculté de Technologie, Université 20 Août 1955-Skikda, BP 26, Route d'El-Hadaiek, Skikda 21000, Algeria.
    Boutebdja M; Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria.
    Setifi F; Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas Sétif 1, Sétif 19000, Algeria.
    Merazig H; Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine 1, Constantine 25000, Algeria.
    Glidewell C; School of Chemistry, University of St Andrews, Fife KY16 9ST, Scotland.
  • Acta crystallographica. Section C, Structural chemistry [Acta Crystallogr C Struct Chem] 2014 Jul; Vol. 70 (Pt 7), pp. 702-6. Date of Electronic Publication: 2014 Jun 17.
  • English
  • In the title compound, catena-poly[bis[(2,2'-bipyridine-κ(2)N,N')(1,1,3,3-tetracyano-2-ethoxypropenido-κN)copper(II)]-μ4-hexanedioato-κ(6)O(1),O(1'):O(1):O(6),O(6'):O(6)], [Cu2(C9H5N4O)2(C6H8O4)(C10H8N2)2]n, the adipate (hexanedioate) dianion lies across a centre of inversion in the space group P1. The Cu(II) centre adopts a distorted form of axially elongated (4+2) coordination, and the Cu(II) and adipate components form a one-dimensional coordination polymer from which the 2,2'-bipyridine and 1,1,3,3-tetracyano-2-ethoxypropenide components are pendent, and where each adipate dianion is bonded to four different Cu(II) centres. The coordination polymer chains are linked into a three-dimensional framework structure by a combination of C-H···N and C-H···O hydrogen bonds, augmented by a π-π stacking interaction.
Additional Information
Publisher: International Union of Crystallography Country of Publication: England NLM ID: 101620313 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 2053-2296 (Electronic) Linking ISSN: 20532296 NLM ISO Abbreviation: Acta Crystallogr C Struct Chem Subsets: PubMed not MEDLINE
Publication: 2014- : Chester : International Union of Crystallography
Original Publication: Malden, MA : John Wiley & Sons Ltd, [2014]-
Keywords: 1,1,3,3-tetracyano-2-ethoxypropenide; 2,2′-bipyridine; adipate; copper(II) complex; crystal structure; one-dimensional coordination polymer; polynitrile anions; π–π stacking interactions
Date Created: 20140704 Date Completed: 20140905 Latest Revision: 20151231