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Crystal structure and Hirshfeld surface analysis of 4-(3-meth-oxy-phen-yl)-2,6-di-phenyl-pyridine.

  • Academic Journal
  • Cheng D; Department of Chemical and Material Engineering, Chaohu College, Chaohu, People's Republic of China.
    Meng XZ; Department of Chemical and Material Engineering, Chaohu College, Chaohu, People's Republic of China.
    Tian F; Department of Chemical and Material Engineering, Chaohu College, Chaohu, People's Republic of China.
    Yan D; Department of Chemical and Material Engineering, Chaohu College, Chaohu, People's Republic of China.
    Wang X; Department of Chemical and Material Engineering, Chaohu College, Chaohu, People's Republic of China.
    Qian X; Department of Chemical and Material Engineering, Chaohu College, Chaohu, People's Republic of China.
    Wang J; Department of Chemical and Material Engineering, Chaohu College, Chaohu, People's Republic of China.
  • Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2022 Aug 23; Vol. 78 (Pt 9), pp. 932-935. Date of Electronic Publication: 2022 Aug 23 (Print Publication: 2022).
  • English
  • The title compound, C 24 H 19 NO, was obtained via the reaction of (1 E ,2 E )-3-(3-meth-oxy-phen-yl)-1-phenyl-prop-2-en-1-one with ethyl 2-oxo-propano-ate, using NH 4 I as a catalyst. The compound crystallizes in the monoclinic space group I 2/ a . In the mol-ecule, the four rings are not in the same plane, the pyridine ring being inclined to the benzene rings by 17.26 (6), 56.16 (3) and 24.50 (6)°. In the crystal, mol-ecules are linked by C-H⋯π inter-actions into a three-dimensional network. To further analyse the inter-molecular inter-actions, a Hirshfeld surface analysis was performed. Hirshfeld surface analysis indicates that the most abundant contributions to the crystal packing are from H⋯H (50.4%), C⋯H/H⋯C (37.9%) and O⋯H/H⋯O (5.1%) inter-actions.
    (© Cheng et al. 2022.)
Additional Information
Publisher: John Wiley & Sons Ltd Country of Publication: England NLM ID: 101648987 Publication Model: eCollection Cited Medium: Print ISSN: 2056-9890 (Print) NLM ISO Abbreviation: Acta Crystallogr E Crystallogr Commun Subsets: PubMed not MEDLINE
Original Publication: West Sussex : John Wiley & Sons Ltd. [2015]-
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Keywords: C—H⋯π inter­actions; Hirshfeld surface; crystal structure; van der Waals inter­actions
Date Created: 20220908 Latest Revision: 20220910
20220910
PMC9443808
10.1107/S2056989022007812
36072513
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