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Synthesis, crystal structure and Hirshfeld surface analysis of aqua-(3-meth-oxy-cinnamato-κ O )bis-(1,10-phenanthroline-κ <sup>2</sup> N , N ')cobalt(II) nitrate.

  • Academic Journal
  • Lehleh A; Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Frères Mentouri Constantine 1, 25017, Constantine, Algeria.
    Boutebdja M; Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Frères Mentouri Constantine 1, 25017, Constantine, Algeria.; Laboratoire Technologie des Matériaux Avancés, École Nationale Polytechnique de Constantine, Nouvelle Ville Universitaire Ali Mendjeli, 25000, Constantine, Algeria.
    Beghidja C; Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Frères Mentouri Constantine 1, 25017, Constantine, Algeria.
    Beghidja A; Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Frères Mentouri Constantine 1, 25017, Constantine, Algeria.
  • Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2022 Oct 11; Vol. 78 (Pt 11), pp. 1113-1117. Date of Electronic Publication: 2022 Oct 11 (Print Publication: 2022).
  • English
  • The title compound, [Co(C 10 H 9 O 3 )(C 12 H 8 N 2 ) 2 (H 2 O)]NO 3 (I), crystallizes in the triclinic space group P with a monomeric [Co(3-meo-cin)(phen) 2 (H 2 O)] + cation and a nitrate anion (3-meo-cin = 3-meth-oxy cinnamic acid) in the asymmetric unit. The Co II ion is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms, the first from a meth-oxy cinnamate ligand and the second from a coordinated water mol-ecule, forming a distorted octa-hedral geometry. Discrete entities of the cation and nitrate anion are formed by water-nitrate O-H⋯O and phen-nitrate C-H⋯O hydrogen bonds. The components are further assembled into chains along the c- axis direction. Layers are than formed by slipped π-π stacking inter-actions parallel to the bc plane. The inter-molecular inter-actions in the crystal structure were qu-anti-fied and analysed using Hirshfeld surface analysis.
    (© Lehleh et al. 2022.)
Additional Information
Publisher: John Wiley & Sons Ltd Country of Publication: England NLM ID: 101648987 Publication Model: eCollection Cited Medium: Print ISSN: 2056-9890 (Print) NLM ISO Abbreviation: Acta Crystallogr E Crystallogr Commun Subsets: PubMed not MEDLINE
Original Publication: West Sussex : John Wiley & Sons Ltd. [2015]-
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Keywords: 3-meth­oxy­cinnamic acid; Hirshfeld surface; N-donor; X-ray diffraction; crystal structure
Date Created: 20221116 Latest Revision: 20221117
20221216
PMC9638979
10.1107/S2056989022009781
36380909
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