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Failure of the IDA in FRET Systems at Close Inter-Dye Distances Is Moderated by Frequent Low κ² Values.

Publication Type: Academic Journal

Source(s): Journal of Physical Chemistry B. Sep2016, Vol. 120 Issue 34, p8845-8862. 18p.

Abstract: Förster resonance energy transfer (FRET) is analyzed in terms of distance- and orientation-dependent interactions between the transition dipole moments of the involved donor and acceptor molecules. However, the ideal dipole approximation (IDA) is known...

Dynamics of Inter-DNA Chain Interaction of Photoresponsive DNA.

Publication Type: Academic Journal

Source(s): Journal of the American Chemical Society. 7/27/2016, Vol. 138 Issue 29, p9001-9004. 4p.

Abstract: Photoresponsive DNA modified with azobenzene is an attractive design molecule for efficient photoregulation of DNA hybridization, which may be used for controlling DNA functions. Although the essential step of photocontrolling DNA is the initial isomer...

Impact of the Inter- and Intramolecular Tertiary Amino Group on the Primary Amino Group in the CO2 Absorption Process.

Publication Type: Academic Journal

Source(s): Industrial & Engineering Chemistry Research. Jul2016, Vol. 55 Issue 26, p7210-7217. 8p.

Abstract: This work has investigated CO2 absorption using 3-(diethylamino)propylamine (DEAPA), a diamine that contains one primary and one tertiary amine in the same molecule. The results are compared with those for the blended amine system of monoethanolamine a...

Three-Step Synthesis of Fluoranthenes through Pd-Catalyzed Inter- and Intramolecular C-H Arylation.

Publication Type: Academic Journal

Source(s): Journal of Organic Chemistry. 5/6/2016, Vol. 81 Issue 9, p3967-3974. 8p.

Abstract: A three-step synthetic method for the preparation of fluoranthenes, involving Miura's intermolecular C-H arylation, nonaflation, and intramolecular C-H arylation, has been developed. Various 1-naphthols and haloarenes were successfully used as substrat...

Inter- and Intramolecular Annulation Strategies toa Cyclopentanone Building Block Containing an All-Carbon QuaternaryStereogenic Center.

Publication Type: Academic Journal

Source(s): Organic Letters. Mar2015, Vol. 17 Issue 6, p1401-1404. 4p.

Abstract: Synthesisof (S)-2-methyl-3-fluorophenylcyclopentanone methyl ester (1S)-1hasbeen achieved by both inter- and intramolecular alkylation reactionson multigram scale, using chiral pool reagents. The intramolecularvariant is a novel example of a chiral bis...

Quantifying the Inter- and Intramolecular Interactionsin Crystalline Phthalic Acid.

Publication Type: Academic Journal

Source(s): Crystal Growth & Design. Nov2014, Vol. 14 Issue 11, p5685-5691. 7p.

Abstract: All inter- and intramolecular interactionsin the crystals of phthalicacid have been quantified from the topology of the electron densitydistribution obtained from low temperature (20 K) X-ray diffractiondata and from theoretical calculations. Using the...

Alkene Diamination Using Electron-Rich Amines: HypervalentIodine-Promoted Inter-/Intramolecular C–N Bond Formation.

Publication Type: Academic Journal

Source(s): Organic Letters. Jul2014, Vol. 16 Issue 14, p3804-3807. 4p.

Abstract: A combined inter-/intramolecularoxidative diamination of terminalalkenes is described that uses a hypervalent iodine oxidant and anucleophilic amine to produce 3-aminoindolines at room temperature.This operationally straightforward and metal-free proto...

Influence of Metal-Peptide Complexation on Fragmentation and Inter-Fragment Hydrogen Migration in Electron Transfer Dissociation.

Publication Type: Academic Journal

Source(s): Journal of the American Society for Mass Spectrometry. Jun2014, Vol. 25 Issue 6, p1029-1039. 11p.

Abstract: The use of metal salts in electrospray ionization (ESI) of peptides increases the charge state of peptide ions, facilitating electron transfer dissociation (ETD) in tandem mass spectrometry. In the present study, K and Ca were used as charge carriers t...

Inter- and Intramolecular Interactions in Some Bromo-and Tricyanovinyl-Substituted Thiophenes and Ethylenedioxythiophenes.

Publication Type: Academic Journal

Source(s): Crystal Growth & Design. Mar2014, Vol. 14 Issue 3, p916-922. 7p.

Abstract: Wereport herein on the competing inter- and intramolecular interactionsin seven structurally related thiophene and ethyelenedioxythiophene(EDOT) molecules, substituted with bromine and/or tricyanovinyl (TCV)groups in various combinations, using single ...

Gold(I)-Catalyzed Inter- and Intramolecular Additions of Carbonyl Compounds to Allenenes.

Publication Type: Academic Journal

Source(s): Organic Letters. Mar2016, Vol. 18 Issue 6, p1410-1413. 4p.

Abstract: The gold(I)-catalyzed intramolecular reaction of allenes with oxoalkenes leads to bicyclo[6.3.0]undecane ring systems, although in the case of terminally disubstituted allenes, seven-membered rings are formed. The related intermolecular addition of ald...