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Phosphine Addition to Pyruvoyl Ligands of Iron Complexes: Formation of Zwitterionic Metallalactones.
Publication Type: Academic Journal
Source(s): Organometallics; Jan2009, Vol. 28 Issue 1, p216-224, 9p
New Organic–Inorganic Hybrid Materials based on DTDH-TTP and Paramagnetic Isothiocyanato Complex Anion: (DTDH-TTP)2[Cr(phen)(NCS)4]·CH2Cl2
Publication Type: Academic Journal
Source(s): Synthetic Metals. Apr2003, Vol. 137 Issue 1-3, p1177. 3p.
Temperature dependence of the IR reflectance spectra of molecular crystals: κ-(EDDH-TTP)3[Cr(phen)(NCS)4]·2CH2Cl2 and κ21-(BDH-TTP)5[Cr(phen)(NCS)4]2·2CH2Cl2
Publication Type: Academic Journal
Source(s): Journal of Molecular Structure. Jun2003, Vol. 651-653, p683. 5p.
Abstract: Polarised IR reflectance spectra of two organic conductors formed by tetrathiapentalene-derived donors and paramagnetic transition metal complex anions, κ-(EDDH-TTP)3[Cr(phen)(NCS)4]·2CH2Cl2 and κ21-(BDH-TTP)5[Cr(phen)(NCS)4]2·2CH2Cl2, with κ-type stru...
Weak ferromagnetism of (BDH-TTP)[M(isoq)2(NCS)4] (M = Cr: Fe; isoq = isoquinoline)
Publication Type: Academic Journal
Source(s): Synthetic Metals. Apr2003, Vol. 137 Issue 1-3, p1195. 2p.
trans -Bis(2,2'-di-pyridyl-amine-κ 2 N , N ')-bis-(1,1,3,3-tetra-cyano-2-eth-oxy-propenido-κ N )copper(II).
Publication Type: Academic Journal
Source(s): IUCrData [IUCrdata] 2022 Dec 23; Vol. 7 (Pt 12), pp. x221180. Date of Electronic Publication: 2022 Dec 23 (Print Publication: 2022).
Abstract: The title compound, [Cu(C 9 H 5 N 4 O) 2 (C 10 H 9 N 3 ) 2 ], was synthesized solvothermally. The complex exhibits a distorted octa-hedral coordination geometry. The Cu II atom is located on an inversion centre. The distorted octahedral CuN 6 coordinat...
Concomitant dimorphism in poly[di-μ-azido-(5,5'-dimethyl-2,2'-bipyridine)iron(II)].
Publication Type: Academic Journal
Source(s): Acta crystallographica. Section C, Structural chemistry [Acta Crystallogr C Struct Chem] 2022 Aug 01; Vol. 78 (Pt 8), pp. 449-454. Date of Electronic Publication: 2022 Jul 21.
Abstract: The title metal-organic polymer, catena-poly[[(5,5'-dimethyl-2,2'-bipyridine-κ 2 N,N')iron(II)]-di-μ-azido-κ 2 N 1 :N 3 -[(5,5'-dimethyl-2,2'-bipyridine-κ 2 N,N')iron(II)]-di-μ-azido-κ 2 N 1 :N 1 ], [Fe(N 3 ) 2 (C 12 H 12 N 2 )] n , features alternatin...
A rare example of a double metamagnetic transition leading to 2D and 3D long-range order in the two-dimensional pyrazine- and azido-bridged cobalt(II) compound [Co(pyz)(N 3 ) 2 ].
Publication Type: Academic Journal
Source(s): Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2022 Apr 05; Vol. 51 (14), pp. 5617-5623. Date of Electronic Publication: 2022 Apr 05.
Abstract: The synthesis, characterization, crystal structure and detailed magnetic properties of a pyrazine (pyz) and azido (N 3 ) bridged cobalt(II) compound of formula [Co(N 3 ) 2 (pyz)] (1) are reported. Compound 1 shows a layered structure formed by Co(II) c...
catena -Poly[[bis-(quinolin-8-amine-κ 2 N , N ')cadmium(II)]-μ-cyanido-κ 2 N : C -[dicyanidonickel(II)]-μ-cyanido-κ 2 C : N ].
Publication Type: Academic Journal
Source(s): IUCrData [IUCrdata] 2021 Jun 08; Vol. 6 (Pt 6), pp. x210568. Date of Electronic Publication: 2021 Jun 08 (Print Publication: 2021).
Abstract: In the title compound, [CdNi(C 9 H 8 N 2 ) 2 (CN) 4 ] n , the Cd and Ni atoms both lie on centres of inversion in space group P 2 1 / c . The Cd atom is coordinated by two bidentate quinolin-8-amine ligands and by the N atoms of tw...
Synthesis, crystal structure and Hirshfeld surface analysis of bis-{2-[(pyridin-2-yl)amino]-pyridinium} tetra-cyano-nickelate(II).
Publication Type: Academic Journal
Source(s): Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2020 Oct 30; Vol. 76 (Pt 11), pp. 1794-1798. Date of Electronic Publication: 2020 Oct 30 (Print Publication: 2020).
Abstract: In the title mol-ecular salt, (C 10 H 10 N 3 ) 2 [Ni(CN) 4 ], the dihedral angle between the pyridine rings in the cation is 1.92 (13)° and the complete anion is generated by a crystallographic centre of symmetry. An intra-molecular N-H⋯N hydrogen bond...
Bis[tris-(pyridin-2-yl)amine]-iron(II) tris-(di-cyano-methyl-idene)methane-diide.
Publication Type: Academic Journal
Source(s): IUCrData [IUCrdata] 2020 Sep 25; Vol. 5 (Pt 9), pp. x201278. Date of Electronic Publication: 2020 Sep 25 (Print Publication: 2020).
Abstract: In the title compound, [Fe{(C 5 H 4 N) 3 N} 2 ][C{C(CN) 2 } 3 ], both ions lie across centres of inversion, with the anion being statistically disordered over two sets of atomic sites having equal occupancy. The cation and anion have approximate and 32...