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  • Publisher: american chemical society
  • Language: english
  • Publication: journal of physical chemistry a
  • Subject: nanocomposite materials
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    • Large effects of ion pairing and protonic-hydridic bonding on the stereochemistry and basicity of crown-, azacrown-, and cryptand-222-potassium salts of anionic tetrahydride complexes of iridium(III).

    Publication Type: Academic Journal

    Source(s): Inorganic chemistry [Inorg Chem] 2002 Jun 03; Vol. 41 (11), pp. 2995-3007.

    Abstract: The compounds [K(Q)][IrH(4)(PR(3))(2)] (Q = 18-crown-6, R = Ph, (i)Pr, Cy; Q = aza-18-crown-6, R = (i)Pr; Q = 1,10-diaza-18-crown-6, R = Ph, (i)Pr, Cy; Q = cryptand-222, R = (i)Pr, Cy) were formed in the reactions of IrH(5)(PR(3))(2) with KH and Q. In ...

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