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    • Large effects of ion pairing and protonic-hydridic bonding on the stereochemistry and basicity of crown-, azacrown-, and cryptand-222-potassium salts of anionic tetrahydride complexes of iridium(III).

    Publication Type: Academic Journal

    Source(s): Inorganic chemistry [Inorg Chem] 2002 Jun 03; Vol. 41 (11), pp. 2995-3007.

    Abstract: The compounds [K(Q)][IrH(4)(PR(3))(2)] (Q = 18-crown-6, R = Ph, (i)Pr, Cy; Q = aza-18-crown-6, R = (i)Pr; Q = 1,10-diaza-18-crown-6, R = Ph, (i)Pr, Cy; Q = cryptand-222, R = (i)Pr, Cy) were formed in the reactions of IrH(5)(PR(3))(2) with KH and Q. In ...

    Synthesis and structural/physical properties of U3Fe2Ge7: a single-crystal study.

    Publication Type: Academic Journal

    Source(s): Inorganic chemistry [Inorg Chem] 2015 Oct 05; Vol. 54 (19), pp. 9646-55. Date of Electronic Publication: 2015 Sep 15.

    Abstract: A single crystal of U3Fe2Ge7 was synthesized by the tin-flux method, and its structural and electronic properties were studied. The compound crystallizes in the orthorhombic crystal structure of La3Co2Sn7 type with two Wyckoff sites for the U atoms. U3...

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