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Versatile MXene composite probe-mediated homogeneous electrochemiluminescence biosensor with integrated signal transduction and near-infrared modulation strategy for concanavalin A detection.
Publication Type: Academic Journal
Source(s): Mikrochimica acta [Mikrochim Acta] 2023 Aug 30; Vol. 190 (9), pp. 372. Date of Electronic Publication: 2023 Aug 30.
Abstract: Based on the highly specific interaction between concanavalin A (Con A) and glucose (Glu), a competitive electrochemiluminescence (ECL) biosensor was constructed for ultrasensitive detection of Con A. Nanocomposites with excellent electrocatalytic and ...
Ratiometric electrochemical OR gate assay for NSCLC-derived exosomes.
Publication Type: Academic Journal
Source(s): Journal of nanobiotechnology [J Nanobiotechnology] 2023 Mar 24; Vol. 21 (1), pp. 104. Date of Electronic Publication: 2023 Mar 24.
Abstract: Non-small cell lung cancer (NSCLC) is the most common pathological type of LC and ranks as the leading cause of cancer deaths. Circulating exosomes have emerged as a valuable biomarker for the diagnosis of NSCLC, while the performance of current electr...
Electrochemical reactor dictates site selectivity in N-heteroarene carboxylations.
Publication Type: Academic Journal
Source(s): Nature [Nature] 2023 Mar; Vol. 615 (7950), pp. 67-72. Date of Electronic Publication: 2023 Jan 05.
Abstract: Pyridines and related N-heteroarenes are commonly found in pharmaceuticals, agrochemicals and other biologically active compounds 1,2 . Site-selective C-H functionalization would provide a direct way of making these medicinally active products 3-5 . Fo...
Introduction to synthetic electrochemistry: new tricks for an old discipline.
Publication Type: Editorial & Opinion
Source(s): Organic & biomolecular chemistry [Org Biomol Chem] 2023 Jan 04; Vol. 21 (2), pp. 221-222. Date of Electronic Publication: 2023 Jan 04.
Estimating Average Velocities of Particle Arrival Using the Time Duration of the Current Signal in Stochastic Blocking Electrochemistry.
Publication Type: Academic Journal
Source(s): Analytical chemistry [Anal Chem] 2022 Dec 06; Vol. 94 (48), pp. 16560-16569. Date of Electronic Publication: 2022 Nov 23.
Abstract: In stochastic blocking electrochemistry, microparticles generate individual current steps when they adsorb on a microelectrode and decrease the current and flux of a redox mediator reacting at the surface. The amplitude of the current step informs on p...
Tuning Benzylic C−H Functionalization of (Thio)xanthenes with Electrochemistry.
Publication Type: Academic Journal
Source(s): Molecules. Aug2023, Vol. 28 Issue 16, p6139. 14p.
Abstract: Here, we report a tunable electrochemical benzylic C−H functionalization of (thio)xanthenes with terminal alkynes and nitriles in the absence of any catalyst or external chemical oxidant. The benzylic C−H functionalization can be well controlled by var...
Facilitated OH¯ diffusion via bubble motion and water flow in a novel electrochemical reactor for enhancing homogeneous nucleation of CaCO 3 .
Publication Type: Academic Journal
Source(s): Water research [Water Res] 2023 Aug 15; Vol. 242, pp. 120195. Date of Electronic Publication: 2023 Jun 07.
Abstract: Electrochemistry is a potential method for water softening. An essential disadvantage is OH¯ ions from water electrolysis accumulate on cathode surface, inducing the generation of the insulating CaCO 3 layer and then interrupting the electrochemical re...
Electrochemistry-Driven Interphase Doubly Protects Graphite Cathodes for Ultralong Life and Fast Charge of Dual-Ion Batteries.
Publication Type: Academic Journal
Source(s): ChemSusChem [ChemSusChem] 2023 Jul 07; Vol. 16 (13), pp. e202300324. Date of Electronic Publication: 2023 Apr 27.
Abstract: Dual-ion batteries (DIBs) with graphite as cathode material, show superiority in terms of sustainability, affordability, and environmental impact over Li-ion batteries that rely on transition-metal based cathodes. However, graphite cathodes severely su...
Elucidation of the environmental reductive metabolism of the herbicide tritosulfuron assisted by electrochemistry and mass spectrometry.
Publication Type: Academic Journal
Source(s): Chemosphere [Chemosphere] 2023 Jul; Vol. 330, pp. 138687. Date of Electronic Publication: 2023 Apr 17.
Abstract: The environmental impact of pesticides and other pollutants is, to a great extent, determined by degradation and accumulation processes. Consequently, degradation pathways of pesticides have to be elucidated before approval by the authorities. In this ...
A Gauss's law analysis of redox active adsorbates on semiconductor electrodes: The charging and faradaic currents are not independent.
Publication Type: Academic Journal
Source(s): Proceedings of the National Academy of Sciences of the United States of America [Proc Natl Acad Sci U S A] 2022 Sep 06; Vol. 119 (36), pp. e2202395119. Date of Electronic Publication: 2022 Aug 29.
Abstract: A detailed framework for modeling and interpreting the data in totality from a cyclic voltammetric measurement of adsorbed redox monolayers on semiconductor electrodes has been developed. A three-layer model consisting of the semiconductor space-charge...